Vinyliden-Uebergangsmetallkomplexe. XXVI. Synthese und Struktur kationischer Carbonyl-, Alken-, Vinyliden-, Alkinyl- und Alkin-Rhodiumkomplexe mit der Baueinheit trans-iPr3)2>

DOI: 10.1016/0022-328X(93)83142-I

Source and publish data:

Journal of Organometallic Chemistry p. 163 - 176 (1993)

Update date:2022-08-04

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Authors:

Nuernberg, Oliver

Werner, Helmut

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Article abstract of DOI:10.1016/0022-328X(93)83142-I

The complex trans-PF6 (2) was prepared from <(η³-C3H5)Rh(PⁱPr3)2> (1), NH4PF6 and CO or from 1 and NH4PF6 in presence of an excess of methanol.With an excess of CO, the dicarbonyl and tricarbonyl compounds trans-

Full text of DOI:10.1016/0022-328X(93)83142-I

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Product name:{Rh(C₅H₅N)2(P(CH(CH₃)2)3)2}⁽¹⁺⁾*BF₄^(1-)={Rh(C₅H₅N)2(P(CH(CH₃)2)3)2}BF₄

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