SYNTHESIS AND APPLICATION OF CHIRAL BISPHOSPHINE LIGANDS CONTAINING A HETERO-FUNCTIONAL GROUP

DOI: 10.1016/S0957-4166(00)80084-1

Source and publish data:

Tetrahedron Asymmetry p. 2287 - 2290 (1993)

Update date:2022-08-02

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Authors:

Yamazaki, Akira

Morimoto, Toshiaki

Achiwa, Kazuo

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Article abstract of DOI:10.1016/S0957-4166(00)80084-1

New chiral bisphosphine ligands bearing hetero-functional groups were prepared by the use of asymmetric Diels-Alder reaction and silver-ion catalyzed rearrangement as key steps.The bisphosphines, especially bearing a carboxyl group, were found to be efficient ligands for palladium-catalyzed asymmetric allylic alkylation.

Full text of DOI:10.1016/S0957-4166(00)80084-1

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