The use of 1,2-trans-cyclohexanediol as an efficient chiral auxiliary for the asymmetric cyclopropanation of allylic ethers

DOI: 10.1016/S0040-4039(00)79275-6

Source and publish data:

Tetrahedron Letters p. 7157 - 7160 (1993)

Update date:2022-08-05

Topics:

Authors:

Charette

Marcoux Marcoux

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Article abstract of DOI:10.1016/S0040-4039(00)79275-6

A new and simple chiral auxiliary derived from optically pure 1,2-trans-cyclohexanediol was developed for the asymmetric Simmons-Smith cyclopropanation of substituted allylic alcohols. Excellent yields and diastereoselectivities were obtained with a variety of olefins.

Full text of DOI:10.1016/S0040-4039(00)79275-6

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