The use of 1,2-trans-cyclohexanediol as an efficient chiral auxiliary for the asymmetric cyclopropanation of allylic ethers

DOI: 10.1016/S0040-4039(00)79275-6

Source and publish data:

Tetrahedron Letters p. 7157 - 7160 (1993)

Update date:2022-08-05

Topics:

Authors:

Charette

Marcoux Marcoux

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79275-6

A new and simple chiral auxiliary derived from optically pure 1,2-trans-cyclohexanediol was developed for the asymmetric Simmons-Smith cyclopropanation of substituted allylic alcohols. Excellent yields and diastereoselectivities were obtained with a variety of olefins.

Full text of DOI:10.1016/S0040-4039(00)79275-6

Products guided by the article

Product name:(1R,2R)-2-(triisopropylsilyloxy)cyclohexanol

Cas No:153996-23-7

R&D Labs maybe for 153996-23-7

Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao
YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China

Relevant to this article

Stereoselective synthesis of the C3-C12 subunit of laulimalide

Doi:10.1016/j.tetlet.2013.12.040
(2014)
Asymmetric syntheses of (2r,4s)-4-amino-4-carboxy-2-methylpyrrolidine and (2r, 4s)-4-amino-2-carboxy-2-ethyl-pyrrolidine as novel 2-alkyl-substituted (-)-cucurbitine analogues

Doi:10.3987/COM-95-7277
(1996)
Pd(0)-catalyzed regio- and stereoselective cyclization of alkynes: Selective synthesis of (E)-4-(isobenzofuran-1(3H)-ylidene)-1,2,3,4- tetrahydroisoquinolines and aze/oxepinoindoles

Doi:10.1039/c3ob42314j
(2014)
Synthesis of [³⁵S]phosphorothionate insecticides: The example of [³⁵S]fenthion

Doi:10.1002/jlcr.2580340110
(1994)
New synthetic approach to (o-hydroxyphenyl)methylphosphonic acid derivatives

Doi:10.1070/mc2003v013n04abeh001784
(2003)
Bis(pentafluorosulfanyl)phenyl azide as an expeditious tool for click chemistry toward antitumor pharmaceuticals

Doi:10.1002/cmdc.201400059
(2014)

Article Doi