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Asymmetric Hetero Diels-Alder Reaction Catalyzed by Stable and Easily Prepared CAB Catalyst

DOI: 10.1016/S0040-4020(01)80812-7

Source and publish data:

Tetrahedron p. 979 - 988 (1994)

Update date:2022-07-29

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Authors:

Gao, QuingzhiGao, Quingzhi

Ishihara, KazuakiIshihara, Kazuaki

Maruyama, TohruMaruyama, Tohru

Mouri, MakotoMouri, Makoto

Yamamoto, HisashiYamamoto, Hisashi

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Article abstract of DOI:10.1016/S0040-4020(01)80812-7

A stable chiral (acyloxy)borane (CAB) complex is prepared in situ by mixing a tartaric acid derivative and arylboronic acids at room temperature.A solution of the catalyst is effective in catalyzing hetero Diels-Alder reactions to produce dihydropyrone derivatives of high optical purities.

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Full text of DOI:10.1016/S0040-4020(01)80812-7

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