Journal of the Chemical Society. Chemical communications p. 25 - 26 (1994)
Update date:2022-08-04
Topics:
Rajamannar, Thennati
Balasubramanian, Kalpattu Kup.
Wieland-Miescher ketone analogues are prepared by monoalkylation of cyclohexane-1,3-dione with bromomethylcycloalkenyl bromides followed by annulation with methyl vinyl ketone; they undergo 5-exo-trig competitive intramolecular radical addition to the keto and enone olefins to give angularly fused carbocycles and propellanes, respectively.
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Doi:10.1039/P19940000497
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