Investigation of the stereochemistry of the [3.3]-sigmatropic rearrangement of the sp-isomer of 2-allylthio-5-acetyl-6-methyl-4-(2-nitrophenyl)-3-cyano-1,4-dihydropyridine

DOI: 10.1007/BF02291939

Source and publish data:

Chemistry of Heterocyclic Compounds p. 557 - 565 (1997)

Update date:2022-07-30

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Authors:

Nesterov

Rodinovskaya

Shestopalov

Struchkov

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Article abstract of DOI:10.1007/BF02291939

The reaction of the syn-periplanar conformer (the sp-isomer) of morpholinium 5-acetyl-6-methyl-4-(2-nitrophenyl)-3-cyano-1,4-dihydropyridine-2-thiolate with allyl bromide proceeds regio- and stereoselectively with the formation of the sp-isomer of the sub

Full text of DOI:10.1007/BF02291939

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