Investigation of the stereochemistry of the [3.3]-sigmatropic rearrangement of the sp-isomer of 2-allylthio-5-acetyl-6-methyl-4-(2-nitrophenyl)-3-cyano-1,4-dihydropyridine

DOI: 10.1007/BF02291939

Source and publish data:

Chemistry of Heterocyclic Compounds p. 557 - 565 (1997)

Update date:2022-07-30

Topics:

Authors:

Nesterov

Rodinovskaya

Shestopalov

Struchkov

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF02291939

The reaction of the syn-periplanar conformer (the sp-isomer) of morpholinium 5-acetyl-6-methyl-4-(2-nitrophenyl)-3-cyano-1,4-dihydropyridine-2-thiolate with allyl bromide proceeds regio- and stereoselectively with the formation of the sp-isomer of the sub

Full text of DOI:10.1007/BF02291939

Products guided by the article

Product name:5-Acetyl-2-allylsulfanyl-6-methyl-4-(2-nitro-phenyl)-1,4-dihydro-pyridine-3-carbonitrile

Cas No:155686-78-5

R&D Labs maybe for 155686-78-5

Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,
Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING

Relevant to this article

Palladium-catalyzed allylation of pyrimidine-2,4-diones (uracils) and of 6-membered heterocyclic ambident sulfur nucleophiles

Doi:10.1016/S0040-4020(01)90197-8
(1993)
Synthesis and anticancer activity of 2-substituted 2,3-dihydro-1,3,2-benzoxazaphosphorin-4-one and its 2-oxide derivatives

Doi:10.1002/ardp.19943270408
(1994)
Synthesis of pentafluorophenylthiohydantoin derivatives of adducts formed with dl-valine by acrylonitrile and cyanoethylene oxide

Doi:10.1016/S0040-4039(00)73094-2
(1994)
Complexes of polyhydro-2,2'-bipyridines with molybdenum and tungsten carbonyls

Doi:10.1016/0022-328X(94)88119-7
(1994)
Design, Synthesis, and Structure-Activity Relationship of Tetrahydropyrido[4,3-d]pyrimidine Derivatives as Potent Smoothened Antagonists with in Vivo Activity

Doi:10.1021/acschemneuro.7b00153
(2017)
Exploring the reactivity of 1,5-disubstituted sulfonyl-triazoles: Thermolysis and Rh(II)-catalyzed synthesis of α-sulfonyl nitriles This article is dedicated to Professor Paul Wender for both his creative contributions to synthetic organic chemistry and u

Doi:10.1016/j.tet.2013.05.048
(2013)

Article Doi