Complexes of polyhydro-2,2'-bipyridines with molybdenum and tungsten carbonyls

DOI: 10.1016/0022-328X(94)88119-7

Source and publish data:

Journal of Organometallic Chemistry p. 157 - 160 (1994)

Update date:2022-07-30

Topics:

Authors:

Bokorny, Stefan

Connor, Joseph A.

Kaspar, Harald

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Article abstract of DOI:10.1016/0022-328X(94)88119-7

Reduction of 2,2'-bipyridine with tin in hydrochloric acid produces both 2-(2'-piperidinyl) pyridine and (1,2,3,6-tetrahydro)-2,2'-bipyridine, which have been characterised by (IR, NMR, and UV) spectroscopy.Tetracarbonyl-molybdenum and -tungsten complexes of these ligands exhibit a solvatochromic behaviour very similar to that of the analogous 2,2'-bipyridine complexes.Key words: Molybdenum; Tungsten; Solvatochromism; Charge transfer; Electronic; Bipyridine

Full text of DOI:10.1016/0022-328X(94)88119-7

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