Bulletin of the Chemical Society of Japan p. 599 - 602 (1994)
Update date:2022-09-26
Topics:
Kotsuki, Hiyoshizo
Yamaguchi, Tadashi
Ohno, Keiji
Ichikawa, Yoshikatsu
Ochi, Masamitsu
The reactions of α-trimethylsiloxy-, α-methoxy-, and α-ethoxystyrene with dimethyl acetylenedicarboxylate (DMAD) and dimethyl fumarate (DMFM) have been investigated.With DMAD the 1:1 Diels-Alder and the 1:2 Diels-Alder ene adducts were obtained, while the reaction with DMFM gave novel open-chain adducts through alkyl group migration and incorporation of the solvent.
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