Cyanide and methylisocyanide complexes of rhenium(I) (X=Cl or CN; dppe=Ph2PCH2CH2PPh2) and trans- (X=H, F, Cl or CN): crystal structures of trans- (X=H or Cl)

Article abstract of DOI:10.1016/0022-328X(94)80081-2

Reaction of trans- (dppe=Ph2PCH2PPh2) with CN gives (1) which, upon further reaction with CN, forms (2) which is readily oxidized to (3).Treatment of 1 with