Silylmethylations of C60 with Grignard Reagents: Selective Synthesis of HC60CH2SiMe2Y and C60(CH2SiMe2Y)2 with Selection of Solvents

DOI: 10.1021/jo00085a007

Source and publish data:

Journal of Organic Chemistry p. 1246 - 1248 (1994)

Update date:2022-08-05

Topics:

Authors:

Nagashima, Hideo

Terasaki, Hiroshi

Kimura, Eiji

Nakajima, Katsumasa

Itoh, Kenji

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Article abstract of DOI:10.1021/jo00085a007

Addition reactions of Me2SiYCH2MgCl (1) to C60 provided two products, HC60CH2SiYMe2 (2) and 2C60 (3) (Y = Me, H, CH=CH2, Ph, O-iPr).Selective preparation of either 2 or 3 was accomplished by selection of the solvent; 2 was formed in THF, wherea

Full text of DOI:10.1021/jo00085a007

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