HIGHLY REGIOSELECTIVE PALLADIUM-MEDIATED SUBSTITUTION OF ALLYLIC AND DIENYLIC CYCLIC CARBONATES

DOI: 10.1016/0040-4039(94)85219-7

Source and publish data:

Tetrahedron Letters p. 2357 - 2360 (1994)

Update date:2022-08-02

Topics: Substitution Palladium catalyst Regioselective Experimental terms Allylic Cyclic carbonates

Authors:

Kang, Suk-Ku

Park, Dong-Chul

Jeon, Jae-Ho

Rho, Ho-Sik

Yu, Chan-Mo

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Article abstract of DOI:10.1016/0040-4039(94)85219-7

Reaction of chiral allylic and dienylic cyclic carbonates with various nucleophiles in the presence of (PPh3)4Pd as a catalyst afforded α-, γ-, or ε-substituted products with high regio-, (E)-stereo-, and diastereoselectivity depending on nucleophiles.

Full text of DOI:10.1016/0040-4039(94)85219-7

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