Tetrahedron Letters p. 2357 - 2360 (1994)
Update date:2022-08-02
Topics: Substitution Palladium catalyst Regioselective Experimental terms Allylic Cyclic carbonates
Kang, Suk-Ku
Park, Dong-Chul
Jeon, Jae-Ho
Rho, Ho-Sik
Yu, Chan-Mo
Reaction of chiral allylic and dienylic cyclic carbonates with various nucleophiles in the presence of (PPh3)4Pd as a catalyst afforded α-, γ-, or ε-substituted products with high regio-, (E)-stereo-, and diastereoselectivity depending on nucleophiles.
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