Stereoselective Synthesis of 2,6-Disubstituted Piperidine Alkaloids via TiCl4 Induced Iminium Ion Cyclization of α-Cyanoamines

DOI: 10.1016/S0040-4039(00)73244-8

Source and publish data:

Tetrahedron Letters p. 3581 - 3582 (1994)

Update date:2022-08-04

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Authors:

Yang, Teng-Kuei

Teng, Tsung-Fan

Lin, Jyh-Hwa

Lay, Yen-Yuan

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Article abstract of DOI:10.1016/S0040-4039(00)73244-8

The stereoselective cyclization of an α-cyanoamine containing a vinyl group induced by TiCl4 in a methylene chloride solution, produces cis 2,6-dialkylpiperidine; whereas a similar reaction of an α-cyanoamine containing a silyl substituted vinyl group gav

Full text of DOI:10.1016/S0040-4039(00)73244-8

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