Stereoselective Synthesis of 2,6-Disubstituted Piperidine Alkaloids via TiCl4 Induced Iminium Ion Cyclization of α-Cyanoamines

DOI: 10.1016/S0040-4039(00)73244-8

Source and publish data:

Tetrahedron Letters p. 3581 - 3582 (1994)

Update date:2022-08-04

Topics:

Authors:

Yang, Teng-Kuei

Teng, Tsung-Fan

Lin, Jyh-Hwa

Lay, Yen-Yuan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73244-8

The stereoselective cyclization of an α-cyanoamine containing a vinyl group induced by TiCl4 in a methylene chloride solution, produces cis 2,6-dialkylpiperidine; whereas a similar reaction of an α-cyanoamine containing a silyl substituted vinyl group gav

Full text of DOI:10.1016/S0040-4039(00)73244-8

Products guided by the article

Product name:Benzyl-((E)-1-propyl-4-trimethylsilanyl-but-3-enyl)-amine

Cas No:156969-21-0

R&D Labs maybe for 156969-21-0

Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
Lian Xing Chemical Co.,Ltd.

Contact:0792-8228321

Address:10TH Floor No.121 binjiang Road Xunyang District
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Jiaxing Barton Chemicals

website:http://www.chinabarton.com

Contact:+86-573-82719618

Address:No. 162 Fumin Road, Honghe Town,

Relevant to this article

ASYMMETRICALLY BONDED ? LIGANDS I. HINGING AWAY FROM METAL OF SUBSTITUTED ALLYLS: SYNTHESES OF 1-syn-METHYL AND -PHENYL COMPLEXES, AND THE MOLECULAR STRUCTURES OF ((η-1-Ph-C3H4)Pd(tmeda))BF4, ((η-C5H5)Pd(η-1-Ph-C3H4)), AND ((phen)Mo(CO)2(NCS)(η-1-Ph-C3H4)) AT 185 K

Doi:10.1016/0022-328X(86)82060-5
(1986)
Stereocontrolled synthesis of an epimer of the C(19)-to-C(27) segment of rifamycin S

Doi:10.1002/hlca.19860690311
(1986)
Model studies aimed at the synthesis of Fredericamycin A. A simple o-quinodimethane route to the spiro naphthalene portion

Doi:10.1016/S0040-4039(00)84427-5
(1986)
Design, synthesis and biological evaluation of anthranilamide derivatives as potential factor Xa (fXa) inhibitors

Doi:10.1016/j.bmc.2018.09.012
(2018)
Discovery of BI 99179, a potent and selective inhibitor of type i fatty acid synthase with central exposure

Doi:10.1016/j.bmcl.2011.07.083
(2011)
Photochemical synthesis of C/D-ring synthons of vitamin D

Doi:10.1016/S0040-4039(00)76782-7
(1994)

Article Doi