Reactivity of a four-membered vanadacycle ring supported by bulky silazanate. Regioselective hydrogenation of pyridine

DOI: 10.1021/om00019a011

Source and publish data:

Organometallics p. 2569 - 2571 (1994)

Update date:2022-08-03

Topics:

Authors:

Berno, Pietro

Gambarotta, Sandro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00019a011

The dinuclear {[(Me₃Si)₂N]V[μ-N(SiMe₃)-Si(Me) ₂CH₂]}₂ complex, containing a four-membered metallacyclic ring, has been obtained via reaction of VCl₃(THF)₃ with (Me₃Si)₂NLi. The reactivity of the metallacycle has been investigated with respect to the coordination of bases, hydrogenation, and insertion of alkynes.

Full text of DOI:10.1021/om00019a011

Products guided by the article

Product name:[((CH₃)3Si)2N]V[N(Si(CH₃)3)Si(CH₃)2CH₂C(C₆H₅)C(C₆H₅)](C₅H₅N)

Cas No:157077-59-3

R&D Labs maybe for 157077-59-3

Suzhou Sinosun Imp.&Exp. Corporation

website:http://www.szsinosun.com

Contact:+86-512-63488895,63488616

Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
WENZHOU M&C FOREIGN TRADE CO.,LTD.

Contact:+86-577-88862917

Address:No.8 Liming West Road,Wenzhou,zhejiang,China
Shanghai Massive Chemical Technology Co., Ltd.

website:http://www.massivechem.com/

Contact:+86 21 34943721

Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Shanghai Run-Biotech Co., Ltd.

website:http://www.run-biotech.com

Contact:+86-21-31576854/57171705 / 57171706

Address:second floor, building 3, No.999, jiangyue Road, minghang District, Shanghai, China
WD Silicone Co., Ltd

Contact:+86-27-87204219, +86-27-87215023

Address:2402, HuiGu Space-time Building, 8 Forest Road, East Lake Hi-Tech Development Zone

Relevant to this article

C-H activation of methyl arenes in the MnO₂-mediated aroylation of N-chlorosulfoximines

Doi:10.1021/ol5003016
(2014)
Ultrasonic and spectroscopic studies on hydrogen bonded complexes of aromatic amine and aryl ketones in n-hexane at 303.15 K

Doi:10.1016/j.molliq.2011.07.010
(2011)
Synthesis of 3- and 4-deoxy derivatives of L-rhamnose from 1,2-O-(1-methoxyethylidene)-β-L-rhamnopyranose

Doi:10.1016/0008-6215(94)80045-6
(1994)
Synthesis of methyl 2-(fluoromethyl)-3-fluoroalanine

Doi:10.1055/s-1994-25552
(1994)
Design and synthesis of 4,6-di-tert-butyl-2,3-dihydro-5-benzofuranols as a novel series of antiatherogenic antioxidants

Doi:10.1021/jm030062a
(2003)
Heterogeneous Pt catalysts for reductive amination of levulinic acid to pyrrolidones

Doi:10.1021/cs500757k
(2014)

Article Doi