Synthesis of New Cationic BINAP-Ruthenium(II) Complexes and their Use in Asymmetric Hydrogenation

DOI: 10.1039/c39890001208

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1208 - 1210 (1989)

Update date:2022-08-03

Topics:

Authors:

Mashima, Kazushi

Kusano, Koh-hei

Ohta, Tetsuo

Noyori, Ryoji

Takaya, Hidemasa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890001208

Reaction of 2 (1) and (S)-BINAP gives cationic BINAP-ruthenium complexes of the formula Y (2) (X = Cl, Br, and I; Y = Cl, Br, I, BF4, and BPh4; arene = C6H6 and p-MeC6H4CHMe2) which are efficient catalyst precursors for enantioselective hydrogenation of various prochiral alkenic and ketonic substrates ; a crystal structure of (2) (with X = Cl, Y = BF4) was obtained.

Full text of DOI:10.1039/c39890001208

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{RuCl(C₆H₆)((S)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl)}Cl

Cas No:157262-10-7

R&D Labs maybe for 157262-10-7

Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
Chengdu Herbpurify Co., Ltd

website:http://www.herbpurify.com

Contact:0086-028-85249238

Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China
Lyrin Industrial Corporation Limited

Contact:86-731-82571800

Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China
Suqian Ruixing Chemical Co., Ltd.

Contact:+86-527-80805666（总机）;84836008(销售)

Address:3 Jingsilu, Zone north, Hubin Xincheng Development Park, Suqian, China
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu

Relevant to this article

Palladium(0)-catalyzed cyclopropanation of benzyl bromides via C(sp ³)-H bond activation

Doi:10.1039/c3cc49231a
(2014)
An Inexpensive Air-Stable Titanium-Based System for the Conversion of Esters to Primary Alcohols

Doi:10.1021/jo00129a031
(1995)
METAL-ASSISTED REACTIONS-12. UNUSUAL SELECTIVITY IN THE REDUCTION OF KETONES WITH ZINC OR CADMIUM BIS-TETRAHYDROBORATE/DIMETHYLFORMAMIDE COMPLEX

Doi:10.1016/0040-4020(82)80090-2
(1982)
Continuous photochemical cleavage of linkers for solid-phase synthesis

Doi:10.1021/ol500530q
(2014)
Synthesis of 5-thio-L-fucose-containing disaccharides, as sequence-specific inhibitors, and 2'-fucosyllactose, as a substrate of α-L-fucosidases

Doi:10.1021/jo961725h
(1997)
On The Synthesis of (2S)-Aziridine-2-Carboxylic Acid Containing Peptides

Doi:10.1016/S0040-4020(01)80847-4
(1994)

Article Doi