Synthesis of New Cationic BINAP-Ruthenium(II) Complexes and their Use in Asymmetric Hydrogenation

DOI: 10.1039/c39890001208

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1208 - 1210 (1989)

Update date:2022-08-03

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Authors:

Mashima, Kazushi

Kusano, Koh-hei

Ohta, Tetsuo

Noyori, Ryoji

Takaya, Hidemasa

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Article abstract of DOI:10.1039/c39890001208

Reaction of 2 (1) and (S)-BINAP gives cationic BINAP-ruthenium complexes of the formula Y (2) (X = Cl, Br, and I; Y = Cl, Br, I, BF4, and BPh4; arene = C6H6 and p-MeC6H4CHMe2) which are efficient catalyst precursors for enantioselective hydrogenation of various prochiral alkenic and ketonic substrates ; a crystal structure of (2) (with X = Cl, Y = BF4) was obtained.

Full text of DOI:10.1039/c39890001208

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