Palladium(0)-catalyzed cyclopropanation of benzyl bromides via C(sp 3)-H bond activation

DOI: 10.1039/c3cc49231a

Source and publish data:

Chemical Communications p. 3692 - 3694 (2014)

Update date:2022-08-03

Topics:

Authors:

Mao, Jiangang

Zhang, Shuo-Qing

Shi, Bing-Feng

Bao, Weiliang

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Article abstract of DOI:10.1039/c3cc49231a

A novel and highly efficient Pd(0)-catalyzed domino reaction to prepare cyclopropane derivatives has been established. The process involves a Heck-type coupling reaction and a C(sp³)-H bond activation. Preliminary DFT calculations suggest that a four-membered palladacycle intermediate is involved. This journal is the Partner Organisations 2014.

Full text of DOI:10.1039/c3cc49231a

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