Anionic Phosphine Complexes of Antimony(III) and Bismuth(III) Halogenoanions

DOI: 10.1039/DT9940001753

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1753 - 1758 (1994)

Update date:2022-08-04

Topics:

Authors:

Clegg, William

Elsegood, Mark R. J.

Norman, Nicholas C.

Pickett, Nigel L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940001753

The reaction between BiI3, I and an excess of PMe3Ph afforded the ionic compound the structure of which has been determined by X-ray crystallography.The anion (-) comprises an octahedral bismuth centre bonded to four iodines and two cis phosphine ligands, although there are some significant distortions from idealised octahedral coordination, the origin of which are discussed.From the reaction between SbBr3 and PEt3, the ionic complex was isolated, probably as a result of adventitious hydrolysis, and also characterised by X-ray crystallography.A discrete dinuclear anion (-) is present in this complex with a geometry best described as between face-shared bioctahedral and two square-based pyramids sharing a vertex.

Full text of DOI:10.1039/DT9940001753

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:P(C₆H₅)4⁽¹⁺⁾*BiI₄(P(CH₃)2C₆H₅)2^(1-)=[P(C₆H₅)4][BiI₄(P(CH₃)2C₆H₅)2]

Cas No:157377-29-2

R&D Labs maybe for 157377-29-2

Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Shanghai Apeptide Co., Ltd.

website:http://www.apeptides.com/en/

Contact:+86-21-60871011

Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Hunan Haili Chemical Industry Co.,Ltd.

Contact:+86-731-85521860

Address:No.251, 2nd Section, Furong Road, Changsha,Hunan,China
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.

Relevant to this article

Enantioselective olefin epoxidation using novel biphenyl and binaphthyl azepines and azepinium salts

Doi:10.1016/j.tetasy.2006.08.018
(2006)
Photoinduced electron transfer (PET) promoted cyclisations of 1-[N-alkyl-N-(trimethylsilyl)methyl]amines tethered to proximate olefin: Mechanistic and synthetic perspectives

Doi:10.1016/S0040-4020(01)85300-X
(1994)
Iridium-catalyzed Synthesis of Saturated N-Heterocycles from Aldehydes and SnAP Reagents with Continuous Flow Photochemistry

Doi:10.1021/acs.orglett.8b00611
(2018)
Doi:10.1021/jm00300a005
(1970)
Synthesis and Absolute Configuration of Four Diastereomeric 1-(2-Furyl)-2-aminobutane-1,3-diols

Doi:10.1016/S0040-4020(01)90488-0
(1994)
Two simple and alternative approaches for the synthesis of anticancer active goniothalamin

Doi:10.24820/ark.5550190.p010.461
(2018)

Article Doi