Welcome to LookChem.com Sign In|Join Free

Article Doi

Anionic Phosphine Complexes of Antimony(III) and Bismuth(III) Halogenoanions

DOI: 10.1039/DT9940001753

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1753 - 1758 (1994)

Update date:2022-08-04

Topics:

Authors:

Clegg, WilliamClegg, William

Elsegood, Mark R. J.Elsegood, Mark R. J.

Norman, Nicholas C.Norman, Nicholas C.

Pickett, Nigel L.Pickett, Nigel L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940001753

The reaction between BiI3, I and an excess of PMe3Ph afforded the ionic compound the structure of which has been determined by X-ray crystallography.The anion (-) comprises an octahedral bismuth centre bonded to four iodines and two cis phosphine ligands, although there are some significant distortions from idealised octahedral coordination, the origin of which are discussed.From the reaction between SbBr3 and PEt3, the ionic complex was isolated, probably as a result of adventitious hydrolysis, and also characterised by X-ray crystallography.A discrete dinuclear anion (-) is present in this complex with a geometry best described as between face-shared bioctahedral and two square-based pyramids sharing a vertex.

View More

Products guided by the article

Product name:P(C6H5)4(1+)*BiI4(P(CH3)2C6H5)2(1-)=[P(C6H5)4][BiI4(P(CH3)2C6H5)2]

Cas No:157377-29-2

157377-29-2

R&D Labs maybe for 157377-29-2

Relevant to this article

Hot Product