Tetrahedron p. 8185 - 8194 (1994)
Update date:2022-08-04
Topics: Olefin Photoinduced Electron Transfer (PET) Cyclisations
Pandey, Ganesh
Devi Reddy
Kumaraswamy
Upon PET reaction, amines of type 1 undergo efficient cyclisations to produce pyrrolidines and piperidines. Mechanistically, involvement of delocalised α-silylmethyl amine radical cation as reactive intermediate in such cyclisations are described.
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Doi:10.1039/c4cc09674f
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