Photoinduced electron transfer (PET) promoted cyclisations of 1-[N-alkyl-N-(trimethylsilyl)methyl]amines tethered to proximate olefin: Mechanistic and synthetic perspectives

DOI: 10.1016/S0040-4020(01)85300-X

Source and publish data:

Tetrahedron p. 8185 - 8194 (1994)

Update date:2022-08-04

Topics: Olefin Photoinduced Electron Transfer (PET) Cyclisations

Authors:

Pandey, Ganesh

Devi Reddy

Kumaraswamy

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Article abstract of DOI:10.1016/S0040-4020(01)85300-X

Upon PET reaction, amines of type 1 undergo efficient cyclisations to produce pyrrolidines and piperidines. Mechanistically, involvement of delocalised α-silylmethyl amine radical cation as reactive intermediate in such cyclisations are described.

Full text of DOI:10.1016/S0040-4020(01)85300-X

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