Diversity-oriented asymmetric catalysis (DOAC): Stereochemically divergent synthesis of thiochromanes using an imidazoline-aminophenol-nickel-catalyzed michael/henry reaction

DOI: 10.1021/ol500361w

Source and publish data:

Organic Letters p. 1700 - 1703 (2014)

Update date:2022-08-03

Topics: Nickel-Catalyzed Aminophenol Imidazoline

Authors:

Arai, Takayoshi

Yamamoto, Yushi

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Article abstract of DOI:10.1021/ol500361w

The (S,S)-diphenylethylenediamine-derived imidazoline-aminophenol-Ni complex catalyzed tandem asymmetric Michael/Henry reaction of 2-mercaptobenzaldehydes with β-nitrostyrenes to give the corresponding (2S,3R,4R)-2-aryl-3-nitrothiochroman-4-ols in up to 9

Full text of DOI:10.1021/ol500361w

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