A simple and efficient transformation of fischer carbene complexes into bromomethyl ketones or β-ketoesters

DOI: 10.1016/S0040-4039(98)01732-8

Source and publish data:

Tetrahedron Letters p. 7967 - 7970 (1998)

Update date:2022-08-05

Topics:

Authors:

Concellon, Jose M.

Bernad Jr., Pablo L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)01732-8

Fischer-type carbene complexes react via nucleophilic attack with dibromomethyllithium or haloester lithium enolates to afford bromomethyl ketones or β-ketoesters, respectively.

Full text of DOI:10.1016/S0040-4039(98)01732-8

Products guided by the article

Product name:2-(4-Methoxy-benzoyl)-2-butyl-essigsaeureethylester

Cas No:1575-13-9

R&D Labs maybe for 1575-13-9

Evergreen Chemical Industry Ltd.

Contact:86-553-4918210

Address:6#2-602 Wanhaobailing
Jiangxi Dongbang Pharmaceutical Co., Ltd.

Contact:+86-795-4433603, 4433388

Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
RongCheng Tianyu Technology Co.,Ltd.

Contact:86-631-7519595

Address:220Ping Donghai Road RongChengCity,ShangDong Province China
Zhejiang Sanmei Chemical Industry Co., Ltd

Contact:86-579-87633213

Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203

Relevant to this article

Ruthenium-catalyzed reduction of carbon dioxide to formaldehyde

Doi:10.1021/ja500708w
(2014)
Anion-induced dimerization in p-squaramidocalix[4]arene derivatives

Doi:10.1021/jo500422u
(2014)
Chiral Diaminodiamide Copper(II) Complexes for the Enantioselective Recognition of Amino Acids: Synthesis of the Ligands and Formation Constants

Doi:10.1002/hlca.19860690818
(1986)
Novel 4-(2-(benzo[d]thiazol-2-yl)phenoxy) substituted phthalocyanine derivatives: Synthesis, electrochemical and in situ spectroelectrochemical characterization

Doi:10.1016/j.jorganchem.2014.01.012
(2014)
Synthesis and cytotoxicity studies of novel benzhydrylpiperazine carboxamide and thioamide derivatives

Doi:10.3109/14756366.2013.765416
(2014)
A Practical Approach for Enantio- and Diastereocontrol in the Synthesis of 2,3-Disubstituted Succinic Acid Esters: Synthesis of the pan-Notch Inhibitor BMS-906024

Doi:10.1055/s-0035-1561636
(2016)

Article Doi