A simple and efficient transformation of fischer carbene complexes into bromomethyl ketones or β-ketoesters

DOI: 10.1016/S0040-4039(98)01732-8

Source and publish data:

Tetrahedron Letters p. 7967 - 7970 (1998)

Update date:2022-08-05

Topics:

Authors:

Concellon, Jose M.

Bernad Jr., Pablo L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)01732-8

Fischer-type carbene complexes react via nucleophilic attack with dibromomethyllithium or haloester lithium enolates to afford bromomethyl ketones or β-ketoesters, respectively.

Full text of DOI:10.1016/S0040-4039(98)01732-8

Products guided by the article

Product name:2-(4-Methoxy-benzoyl)-2-butyl-essigsaeureethylester

Cas No:1575-13-9

R&D Labs maybe for 1575-13-9

QINGDAO NEW FLOURISH INTERNATIOANAL TRADE CO., LTD.

Contact:+86 532 80861829

Address:No. 1, Yinchuan East Road, 266061, Qingdao, China
WUHAN RISON TRADING CO.,LTD

Contact:0086-27-83607103/83642615

Address:No.498, Jianshe Ave, Wuhan, China
Tianjin Tensing Fine Chemical Research Develop Centre

Contact:86-022-23718576,13032267585

Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
HAINAN JINYING IMPORT AND EXPORT CO. LTD

Contact:+86-898-32875423

Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA

Relevant to this article

Ruthenium-catalyzed reduction of carbon dioxide to formaldehyde

Doi:10.1021/ja500708w
(2014)
Anion-induced dimerization in p-squaramidocalix[4]arene derivatives

Doi:10.1021/jo500422u
(2014)
Chiral Diaminodiamide Copper(II) Complexes for the Enantioselective Recognition of Amino Acids: Synthesis of the Ligands and Formation Constants

Doi:10.1002/hlca.19860690818
(1986)
Novel 4-(2-(benzo[d]thiazol-2-yl)phenoxy) substituted phthalocyanine derivatives: Synthesis, electrochemical and in situ spectroelectrochemical characterization

Doi:10.1016/j.jorganchem.2014.01.012
(2014)
Synthesis and cytotoxicity studies of novel benzhydrylpiperazine carboxamide and thioamide derivatives

Doi:10.3109/14756366.2013.765416
(2014)
A Practical Approach for Enantio- and Diastereocontrol in the Synthesis of 2,3-Disubstituted Succinic Acid Esters: Synthesis of the pan-Notch Inhibitor BMS-906024

Doi:10.1055/s-0035-1561636
(2016)

Article Doi