Synthesis of (±)-pseudoheliotridane by allylboration of 1-pyrroline

DOI: 10.1007/BF02495581

Source and publish data:

Russian Chemical Bulletin p. 1410 - 1412 (1998)

Update date:2022-08-04

Topics:

Authors:

Gurskii Gurskii

Potapova

Bubnov Bubnov

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Article abstract of DOI:10.1007/BF02495581

Reaction of tricrotylborane with 1-pyrroline proceeds stereoselectively to give (1R*, 1′S*)-2-(1-methylallyl)pyrrolidine. The latter was converted to the pyrrolizidine alkaloid (±)-pseudoheliotridane through hydroboration - oxidation - intramolecular cycl

Full text of DOI:10.1007/BF02495581

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