A Bis(2,6-di-tert-butyl-4-methylphenolato)samarium(II) Complex, .thf

DOI: 10.1107/S0108270193014234

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 1456 - 1458 (1994)

Update date:2022-08-03

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Authors:

Qi, Gui-Zhong

Shen, Qi

Lin, Yong-Hua

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Article abstract of DOI:10.1107/S0108270193014234

The title complex, bis(2,6-di-tert-butyl-4-methylphenolato-O)tris(tetrahydrofuran-O)samarium tetrahydrofuran solvate, .C4H8O, has distorted trigonal bipyramidal geometry around the Sm^II atom.The O(2), O(3) and O(4) atoms of the thf ligands form a plane and the O(1) and O(5) atoms of the aryl groups occupy the apical sites.The Sm--OAr distances Sm--O(1) and Sm--O(5) are 2.318(7) and 2.290(9) Angstroem, respectively.

Full text of DOI:10.1107/S0108270193014234

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