Palladium-catalyzed Chemoselective Reaction of Allylic Carbonate with Nucleoside Bases and Its Application for the Synthesis of Carbocyclic Nucleosides. (-)- and (+)-Carbovirs

Article abstract of DOI:10.1246/cl.1994.1071

Palladium(0)-catalyzed reaction of 2-cyclopenten-1-yl methyl carbonate derivatives with nucleoside bases gave carbocyclic nucleosides chemo- and regioselectively under the neutral reaction conditions.The reaction was effectively used for the synthesis of