Tetrahedron p. 1585 - 1592 (1980)
Update date:2022-08-03
Topics:
Arnould, J.C.
Cossy, J.
Pete, J.P.
The photochemical behaviour of 2-alkylamino 2-cyclohexenones is very sensitive to the nitrogen substituents. α-Ketoazetidines are produced by irradiation of 2-methanesulfonamido-2-cyclohexenones; however a desulfonation and aryl migration process can complete in the case of 2-arenesulfonamido-2-cyclohexenones.Furthermore divinylamine and photo-Fries rearrangements are the main reactions with 2-anilino 2-cyclohexenone and 2-benzoylamido 2-cyclohexenone respectively.
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