Journal of Fluorine Chemistry p. 287 - 292 (1994)
Update date:2022-09-26
Topics:
Zhang, Y. F.
Kirchmeier, Robert L.
Shreeve, Jean'ne M.
Hexafluorobenzene reacts readily with a variety of trimethylsilyl ethers ROSiMe3 (R = CF3CH2, FCH2CH2, H(CF2)nCH2 (n = 2, 4), CF3(CF2)6CH2, CF3(CF2)5CH2CH2, Me3SiOCH2CH2, C6F5OCH2CH2, C6H5, 4-FC6H4) to give from mono- to hexapolyfluoroalkoxy- and polyfluoroaryloxy-benzenes.The structure of C6(OCH2CF3)6 has been confirmed by single-crystal X-ray analysis.The perfluorinated ether C6F5OCF2CF3 may be synthesized from C6F5OCH2CF3 by chlorination and subsequent fluorination with SbF3/SbCl5.The chlorination of 5,6,7,8-tetrafluoro-1,4-benzodioxane is also discussed.
View MoreContact:+86-0512-69209969
Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Suzhou HeChuang Chemical Co.,Ltd.
Contact:+86-512-88800520
Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Jiangxi Dongxu Chemical Science & Technology Co.,Ltd
Contact:+86-791-86899381
Address:Nanchang, Jiangxi, China
Shanghai Sinofluoro Scientific Co., Ltd
Contact:+86-21-64279360
Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
Shanghai PotentPharm Science and Technology Co.,Ltd
Contact:86-021-51969655
Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Doi:10.1021/jo501881y
(2014)Doi:10.1002/ejoc.201301782
(2014)Doi:10.1039/c4cc00034j
(2014)Doi:10.1016/j.tet.2013.11.107
(2014)Doi:10.1248/bpb.b18-00765
(2019)Doi:10.1021/ja01856a053
(1941)
