Mixed Phosphathia Macrocyclic Chemistry: Synthesis and Characterisation of aneP2S2)>(2+) ( M = Pd or Pt) and aneP2S2)>(1+) (Ph2aneP2S2 = 8,12-Diphenyl-1,5-dithia-8,12-diphosphacyclotetradecane)

DOI: 10.1039/DT9940003031

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3031 - 3038 (1994)

Update date:2022-07-29

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Authors:

Champness, Neil R.

Frampton, Christopher S.

Reid, Gillian

Tocher, Derek A.

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Article abstract of DOI:10.1039/DT9940003031

The new diphosphadithia macrocycle 8,12-diphenyl-1,5-dithia-8,12-diphosphacyclotetradecane (Ph2<14>aneP2S2) has been prepared and the meso isomer isolated as white solid.Upon reaction with MCl2 (M = Pd or Pt) in the presence of TlPF6 in refluxing MeCN thi

Full text of DOI:10.1039/DT9940003031

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