Intramolecular Diels-Alder reactions of tethered homo- and heterotrienes. Synthesis of substituted cyclohexenes and six-membered heterocycles

DOI: 10.1016/S0040-4039(98)01829-2

Source and publish data:

Tetrahedron Letters p. 8337 - 8340 (1998)

Update date:2022-08-05

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Authors:

Craig, Donald

Gordon, Richard S.

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Article abstract of DOI:10.1016/S0040-4039(98)01829-2

Intramolecular Diels-Alder reactions of a number of diester-tethered trienes are reported. All-carbon trienes 5, 7 and 13 show little or no selectivity for trans-fused products. Heterotrienes 21 and 25 exhibit good to excellent cis-selectivity, with low to good selectivity for one of the two cis-fused isomers.

Full text of DOI:10.1016/S0040-4039(98)01829-2

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