Anti Aldol Reactions of Lactate-Derived Ketones: Application to the Total Synthesis of (-)-ACRL Toxin IIIB.

DOI: 10.1016/S0040-4039(00)78576-5

Source and publish data:

Tetrahedron Letters p. 9477 - 9480 (1994)

Update date:2022-08-04

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Authors:

Paterson, Ian

Wallace, Debra J.

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Article abstract of DOI:10.1016/S0040-4039(00)78576-5

The fungal polyketide derivative (-)-ACRL toxin IIIB (4) has been prepared in 15 steps (21percent yield) from ketone (S)-7 with 88 percent overall ds.The boron-mediated anti aldol reaction of (S)-7 is used twice in the synthesis, controlling the stereoche

Full text of DOI:10.1016/S0040-4039(00)78576-5

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