Journal of the Chemical Society. Perkin Transactions 2 (2001) p. 1113 - 1124 (1996)
Update date:2022-08-05
Topics: Intramolecular Aqueous stereoselective total synthesis Diels-Alder approach
Naruse, Masaichi
Aoyagi, Sakae
Kibayashi, Chihiro
A chiral approach to (-)-pumiliotoxin C based on an aqueous intramolecular acylnitroso Diels-Alder reaction is described. Upon treatment of the (S)-1,3-diene hydroxamic acid 19, available from L-malic acid, with Pr4NIO4 under the aqu
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