Stereoselective total synthesis of (-)-pumiliotoxin C by an aqueous intramolecular acylnitroso Diels-Alder approach

DOI: 10.1039/P19960001113

Source and publish data:

Journal of the Chemical Society. Perkin Transactions 2 (2001) p. 1113 - 1124 (1996)

Update date:2022-08-05

Topics: Intramolecular Aqueous stereoselective total synthesis Diels-Alder approach

Authors:

Naruse, Masaichi

Aoyagi, Sakae

Kibayashi, Chihiro

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Article abstract of DOI:10.1039/P19960001113

A chiral approach to (-)-pumiliotoxin C based on an aqueous intramolecular acylnitroso Diels-Alder reaction is described. Upon treatment of the (S)-1,3-diene hydroxamic acid 19, available from L-malic acid, with Pr₄NIO₄ under the aqu

Full text of DOI:10.1039/P19960001113

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