Tetrahedron p. 10827 - 10834 (1996)
Update date:2022-08-03
Topics:
Hanessian, Stephen
Conde, Jose J.
Khai, Hoan Huynh
Lou, Boliang
The coupling of 2-(2',3',4',6'-tetra-O-benzyl-β-D-hexopyranosyloxy)-3-methoxypyridin e as well as 2-(2',3',4',6'-tretra-O-benzyl-β-D-hexopyranosyl)-thiopyridylcarbona te, with silylated pyrimidine bases by activation with trimethylsilyl trifluoromethanesulfonate and silver triflate respectively afforded the corresponding 1,2-trans nucleosides with high selectivity.
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(1995)
