Chemistry - A European Journal p. 8801 - 8804 (2016)
Update date:2022-08-02
Topics:
Rao, Yutao
Kim, Jun Oh
Kim, Woojae
Zhong, Guangming
Yin, Bangshao
Zhou, Mingbo
Shinokubo, Hiroshi
Aratani, Naoki
Tanaka, Takayuki
Liu, Shubin
Osuka, Atsuhiro
Kim, Dongho
Song, Jianxin
β-to-β 2,5-Pyrrolylene linked cyclic porphyrin oligomers have been synthesized by Suzuki–Miyaura coupling of 2,5-diborylpyrrole and 3,7-dibromoporphyrin. The cyclic porphyrin oligomers exhibit roughly coplanar structures, strong excitonic coupling, small electrochemical HOMO–LUMO gaps, and ultrafast excitation energy transfer between the neighboring porphyrins via the pyrrolylene bridge.
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Doi:10.1039/c39940002049
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