A new phase transfer reagent for the addition of dichlorocarbene to olefins under mild PTC conditions

Article abstract of DOI:10.1080/00397919908085884

A three-step synthetic route to a novel water soluble phase transfer reagent, Diquat (Dq-Br), viz., 2-benzilidine-N,N,N,N',N',N'- hexaethyl propane-1,3 diammonium dibromide and its utility in various dichlorocarbenations to olefins are described.

Full text of DOI:10.1080/00397919908085884

This article was downloaded by: [York University Libraries]
On: 12 August 2014, At: 12:20
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic Organic
Chemistry
Publication details, including instructions for authors and
subscription information:
http://www.tandfonline.com/loi/lsyc20
A New Phase Transfer Reagent for
the Addition of Dichlorocarbene to
Olefins Under Mild PTC Conditions
J. Paul Jayachandran a & Maw-Ling Wang b
a Department of Chemical Engineering , National Tsing Hua
University , Hsinchu, Taiwan, 300, R.O.C
b Department of Chemical Engineering , National Chung
Cheng University , Chiayi, Taiwan, 621, R.O.C
Published online: 17 Sep 2007.
To cite this article: J. Paul Jayachandran & Maw-Ling Wang (1999) A New Phase Transfer
Reagent for the Addition of Dichlorocarbene to Olefins Under Mild PTC Conditions, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic Organic
Chemistry, 29:23, 4101-4112
To link to this article: http://dx.doi.org/10.1080/00397919908085884
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the information
(the “Content”) contained in the publications on our platform. However, Taylor
& Francis, our agents, and our licensors make no representations or warranties
whatsoever as to the accuracy, completeness, or suitability for any purpose of the
Content. Any opinions and views expressed in this publication are the opinions and
views of the authors, and are not the views of or endorsed by Taylor & Francis. The
accuracy of the Content should not be relied upon and should be independently
verified with primary sources of information. Taylor and Francis shall not be liable
for any losses, actions, claims, proceedings, demands, costs, expenses, damages,

and other liabilities whatsoever or howsoever caused arising directly or indirectly in
connection with, in relation to or arising out of the use of the Content.
This article may be used for research, teaching, and private study purposes. Any
substantial or systematic reproduction, redistribution, reselling, loan, sub-licensing,
systematic supply, or distribution in any form to anyone is expressly forbidden.
Terms & Conditions of access and use can be found at http://www.tandfonline.com/
page/terms-and-conditions