Journal of the American Chemical Society p. 11275 - 11286 (1994)
Update date:2022-08-03
Topics:
Clive, Derrick L. J.
Tao, Yong
Khodabocus, Ahmad
Wu, Yong-Jin
Angoh, A. Ga?tan
Bennett, Sharon M.
Boddy, Christopher N.
Bordeleau, Luc
Kellner, Dont
Kleiner, Galit
Middleton, Donald S.
Nichols, Christopher J.
Richardson, Scott R.
Vernon, Peter G.
Crystalline (±)-fredericamycin A (1) was synthesized using, as a key step, 5-exo-digonal radical closure of selenide 55. The selenide was generated from the corresponding ketone 54, itself assembled from two components: aldehyde 29 and bromonaphthalene 48
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