Organometallics p. 3535 - 3539 (2014)
Update date:2022-08-05
Topics:
Zhao, Hua
Sun, Hongjian
Li, Xiaoyan
When the diphosphinito PCP ligand (Ph2P(C6H 4))2CH2 (1) was treated with Fe(PMe 3)4 and FeMe2(PMe3)4, the Csp3-H activation products [(Ph2P(C 6H4))2CH]Fe(H)(PMe3)2 (2) and [(Ph2P(C6H4))(PhP(C6H 4)2)CH]Fe(PMe3)2 (3) were obtained at room temperature. The generation of product 3 underwent one C sp3-H and one Csp2-H bond activation process. The new iron hydride complex 2 showed good activity in the catalytic hydrosilylation of aldehydes and ketones by using (EtO)3SiH as the hydrogen source under mild conditions. Complexes 2 and 3 were characterized by spectroscopic methods and X-ray diffraction analysis.
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Doi:10.1021/jm00307a040
(1968)Doi:10.1039/c4cc03105a
(2014)Doi:10.3184/174751914X13997396123260
(2014)Doi:10.1039/DT9950000531
(1995)Doi:10.1021/np500233t
(2014)Doi:10.1021/jo01016a012
(1965)
