Platinum(II) Co-ordination Chemistry of Bis(diphenylphosphino)amine

DOI: 10.1039/DT9950000521

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 521 - 530 (1995)

Update date:2022-09-26

Topics:

Authors:

Browning, C. Scott

Farrar, David H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950000521

A spectroscopic and structural examination of the platinum(II) co-ordination chemistry of bis(diphenylphosphino)amine (dppa) and bis(diphenylphosphino)methylamine (dppma) has been made.The complexes , , , , (2+) and (2+) as the chloride, iodide and tetrafluoroborate salts, , trans- and have been prepared.The solid-state structures of 2*MeCN, 2 and trans- have been determined by X-ray crystallography.The crystallographic examination permits a critical evaluation of the nature of the strain in the four-membered rings formed by ligand chelation to a transition-metal centre.Structural and theoretical data suggest that bis(diphenylphosphino)amine chelate complexes should be more strained than the corresponding bis(diphenylphosphino)methane (dppm) complexes.The preference of Pt(II) for binding to dppa rather than dppm implies the formation of a stronger Pt-P bond in complexes of the former ligand.

Full text of DOI:10.1039/DT9950000521

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[bis(diphenylphosphino)amine]dicyanoplatinum(II)

Cas No:161839-84-5

R&D Labs maybe for 161839-84-5

LINAN HAIHUA CHEMICAL CO LTD

Contact:86-571-61063068

Address:LINAN
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Shanghai TBBMed Co.,Ltd

website:http://www.tbbmed.com

Contact:86--21-50498136

Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China
Shandong Wanda Organosilicon New Material Co., Ltd

Contact:+86-21-54177116;54302881

Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
Chinapeptides Co,. Ltd

Contact:+86-021-50792271

Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202

Relevant to this article

Synthesis of novel vitamin D₃ analog with an additional ring annulated to A and seco-B rings

Doi:10.1016/j.steroids.2014.05.016
(2014)
Hydrogen storage in a potassium-ion-bound metal-organic framework incorporating crown ether struts as specific cation binding sites

Doi:10.1002/anie.201404265
(2014)
A synthetic model for the oxygen-evolving complex in Sr²⁺- containing photosystem II

Doi:10.1039/c4cc02349h
(2014)
Radical Cyclization of Oxime Ethers

Doi:10.1021/ja00213a052
(1988)
Synthesis of the ferrocenyl analogue of clotrimazole drug

Doi:10.1016/j.jorganchem.2016.12.009
(2017)
Studies on the Reaction of Thiiranes with Tributyltin Hydride

Doi:10.1021/jo00107a033
(1995)

Article Doi