Efficient cleavage of terminal acetonide group: Chirospecific synthesis of 2,5-Dideoxy-2,5-Imino-D-Mannitol

DOI: 10.1016/0040-4039(94)88373-4

Source and publish data:

Tetrahedron Letters p. 9737 - 9740 (1994)

Update date:2022-08-04

Topics:

Authors:

Park, Ki Hun

Yoon, Yong Jin

Lee, Sang Gyeong

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Article abstract of DOI:10.1016/0040-4039(94)88373-4

Dowex 50W-X8 was efficient catalyst for selective cleavage of terminal actonide including acid-sensitive multifunctional groups. A facile and economically synthesis of DMDP (2,5-dideoxy-2,5-imino-D-mannitol) is described via selective hydrolysis and intramolecular nucleophilic amination.

Full text of DOI:10.1016/0040-4039(94)88373-4

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