Enantiopure 2-Thioxotetrahydro-1,3-O,N-heterocycles from Carbohydrates. 3. Enantiopure C-4 Chiral Oxazine- and Oxazolidine-2-thiones from 3-Deoxy-3-isothiocyanato Sugars

DOI: 10.1021/jo00098a014

Source and publish data:

Journal of Organic Chemistry p. 5565 - 5572 (1994)

Update date:2022-07-29

Topics:

Authors:

Fernandez, Jose M. Garcia

Mellet, Carmen Ortiz

Blanco, Jose L. Jimenez

Fuentes, Jose

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Article abstract of DOI:10.1021/jo00098a014

The synthesis of 3-deoxy-3-isothiocyanato derivatives of D-glucose, D-allose, and D-galactose is reported.The intramolecular cyclization of partially or fully unprotected 3-deoxy-3-isothiocyanates has been found to proceed with total stereocontrol, the ou

Full text of DOI:10.1021/jo00098a014

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