The reactions of tridentate cationic palladium(II) complexes with olefins and nucleophiles

DOI: 10.1016/0022-328X(94)00027-A

Source and publish data:

Journal of Organometallic Chemistry p. 223 - 232 (1995)

Update date:2022-08-04

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Authors:

Kraatz, Heinz-Bernhard

Milstein, David

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Article abstract of DOI:10.1016/0022-328X(94)00027-A

The reaction of the chelating bisphosphine 1,3-bis(dipehnylphosphino)xylene (dppxH) 1 with PdCl2(NCMe)2 gives (dppx)PdCl 3.Analogously, 1,3-bis(bis(p-dimethylaniline)phosphino)xylene (dappxH) 2 yields (dappx)PdCl 4.Halide abstraction with AgBF4 leads clea

Full text of DOI:10.1016/0022-328X(94)00027-A

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Product name:Pd(C₆H₃(CH₂P(C₆H₅)2)2)(C₇H₁₀)⁽¹⁺⁾*BF₄^(1-)=[Pd(C₆H₃(CH₂P(C₆H₅)2)2)(C₇H₁₀)]BF₄

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