Cis-trans isomeric influence on the reactivity of BrMn(CO)2dppmP(OPh)3 towards dialkylthioethers

DOI: 10.1016/0277-5387(94)00249-E

Source and publish data:

Polyhedron p. 425 - 428 (1995)

Update date:2022-09-26

Topics:

Authors:

Diaz, C.

Leal, C.

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Article abstract of DOI:10.1016/0277-5387(94)00249-E

Trans-[BrMn(CO)2(dppm)P(OPh)3] reacts with SR2; R=C2H5 and C3H7 to give the cationic complexes trans-[Mn(CO)2(dppm)P(OPh)3(SR2)]PF6 while from the reaction of cis,cis-[BrMn(CO)2(dppm)P(OPh)3] with the thioether ligands the unaltered dicarbonyl manganese c

Full text of DOI:10.1016/0277-5387(94)00249-E

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Product name:Mn(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)P(OC₆H₅)3(S(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Mn(CO)2((C₆H₅)2PCH₂P(C₆H₅)2)P(OC₆H₅)3(S(C₂H₅)2)]PF₆

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