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Reactions of Chiral Phosphorous Acid Diamides: The Asymmetric Synthesis of Chiral α-Hydroxy Phosphonamides, Phosphonates, and Phosphonic Acids

DOI: 10.1021/jo00109a025

Source and publish data:

Journal of Organic Chemistry p. 931 - 940 (1995)

Update date:2022-08-02

Topics:

Authors:

Blazis, Vincent J.Blazis, Vincent J.

Koeller, Kevin J.Koeller, Kevin J.

Spilling, Christopher D.Spilling, Christopher D.

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Article abstract of DOI:10.1021/jo00109a025

Addition of aldehydes to the anions of chiral phosphorous acid diamides in THF solution gave α-hydroxy phosphonamides in good yield.The diastereoselectivity was strongly dependent upon the diamide used and ranged from poor to good.The phosphorous acid dia

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Full text of DOI:10.1021/jo00109a025

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