Stereospecific Synthesis of 1-Alkylimidazole Derivatives via Mitsunobu Reactions

DOI: 10.1016/S0957-4166(00)86167-4

Source and publish data:

Tetrahedron Asymmetry p. 181 - 184 (1994)

Update date:2022-08-05

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Authors:

Botta, Maurizio

Summa, Vincenzo

Trapassi, Gianna

Monteagudo, Edith

Corelli, Federico

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Article abstract of DOI:10.1016/S0957-4166(00)86167-4

4,5-Dicyanoimidazole has been reacted with racemic and enantiopure alcohols 1 under Mitsunobu conditions to give 1-alkyl-4,5-dicyanoimidazole derivatives 2, which in turn have been transformed by hydrolysis and decarboxylation into 1-alkylimidazoles 4 in

Full text of DOI:10.1016/S0957-4166(00)86167-4

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Product name:(S)-(+)-1-(1-Phenyl-2-propyl)imidazole-4,5-dicarbonitrile

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