Stereochemistry of remote dianion addition to imines. Application to the synthesis of (1S, 8aS)-1-hydroxyindolizidine

DOI: 10.1016/0040-4020(95)00037-9

Source and publish data:

Tetrahedron p. 2865 - 2874 (1995)

Update date:2022-08-03

Topics: Formation of the Iminium Ion Further Functionalization

Authors:

Green, Diana L. C.

Kiddle, James J.

Thompson, Charles M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)00037-9

A stereoselective route to (1S, 8aS)-1-hydroxyindolizidine is reported herein that incorporates as a pivotal step the diastereoselective addition of the dianion of 4-(phenylsulfonyl)butanoic acid (4-PSBA) to a chiral α-benzyloxymethyl imine.

Full text of DOI:10.1016/0040-4020(95)00037-9

Products guided by the article

Product name:(S)-3-((2R,3S)-3-Benzenesulfonyl-1-benzyl-piperidin-2-yl)-3-benzyloxymethoxy-propan-1-ol

Cas No:163041-44-9

R&D Labs maybe for 163041-44-9

AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
LIDE PHARMACEUTICALS LIMITED

website:http://www.lidepharma.com

Contact:+86-25-58409506

Address:Chungking Express Nos.36 Nathan Road，Kowloon, HK
SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City

Relevant to this article

Improved and practical synthesis of [2,4,5-tris(trimethylsilyl)- Phenyl](phenyl)iodonium triflate and utilization as a 1,4-benzdiyne synthon

Doi:10.1002/adsc.201400081
(2014)
Regioselective Oxidative Cleavage of Functionalized Unsymmetric Tetraalkylstannanes via Ozone

Doi:10.1016/0040-4039(94)88057-3
(1994)
Noncovalent functionalization of carbon nanotubes by fluorescent polypeptides: Supramolecular conjugates with pH-dependent absorbance and fluorescence

Doi:10.1166/jnn.2013.7851
(2013)
Assignment of the absolute configuration and total synthesis of (+)-caripyrin

Doi:10.1002/ejoc.201402540
(2014)
(-)-Complanine, an inflammatory substance of marine fireworm: A synthetic study

Doi:10.3762/bjoc.5.12
(2009)
Doi:10.1016/S0040-4020(01)85370-9
(1994)

Article Doi