Stereochemistry of remote dianion addition to imines. Application to the synthesis of (1S, 8aS)-1-hydroxyindolizidine

DOI: 10.1016/0040-4020(95)00037-9

Source and publish data:

Tetrahedron p. 2865 - 2874 (1995)

Update date:2022-08-03

Topics: Formation of the Iminium Ion Further Functionalization

Authors:

Green, Diana L. C.

Kiddle, James J.

Thompson, Charles M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)00037-9

A stereoselective route to (1S, 8aS)-1-hydroxyindolizidine is reported herein that incorporates as a pivotal step the diastereoselective addition of the dianion of 4-(phenylsulfonyl)butanoic acid (4-PSBA) to a chiral α-benzyloxymethyl imine.

Full text of DOI:10.1016/0040-4020(95)00037-9

Products guided by the article

Product name:(S)-3-((2R,3S)-3-Benzenesulfonyl-1-benzyl-piperidin-2-yl)-3-benzyloxymethoxy-propan-1-ol

Cas No:163041-44-9

R&D Labs maybe for 163041-44-9

CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Shochem(Shanghai) Co., Ltd

website:http://www.shochem.com

Contact:021-50800795

Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
guide(suzhou) fine materials co. ltd

Contact:0512-80972173

Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129

Relevant to this article

Improved and practical synthesis of [2,4,5-tris(trimethylsilyl)- Phenyl](phenyl)iodonium triflate and utilization as a 1,4-benzdiyne synthon

Doi:10.1002/adsc.201400081
(2014)
Regioselective Oxidative Cleavage of Functionalized Unsymmetric Tetraalkylstannanes via Ozone

Doi:10.1016/0040-4039(94)88057-3
(1994)
Noncovalent functionalization of carbon nanotubes by fluorescent polypeptides: Supramolecular conjugates with pH-dependent absorbance and fluorescence

Doi:10.1166/jnn.2013.7851
(2013)
Assignment of the absolute configuration and total synthesis of (+)-caripyrin

Doi:10.1002/ejoc.201402540
(2014)
(-)-Complanine, an inflammatory substance of marine fireworm: A synthetic study

Doi:10.3762/bjoc.5.12
(2009)
Doi:10.1016/S0040-4020(01)85370-9
(1994)

Article Doi