Total synthesis of (+)-compactin by a double Michael protocol

DOI: 10.1039/P19950000777

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 777 - 784 (1995)

Update date:2022-07-31

Topics:

Authors:

Hagiwara, Hisahiro

Nakano, Takashi

Kon-no, Masakazu

Uda, Hisashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19950000777

The total synthesis of (+)-compactin 1 has been achieved by employing a double Michael reaction of (R)-1-acetyl-3-(tert-butyldimethylsiloxy)cyclohexene 16 with methyl crotonate as the key reaction.

Full text of DOI:10.1039/P19950000777

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(R)-3-(tert-Butyl-dimethyl-silanyloxy)-1-(1-trimethylsilanyloxy-vinyl)-cyclohexene

Cas No:163879-35-4

R&D Labs maybe for 163879-35-4

Shanghai Yuanding Chem. Sci. & Tech. Co., Ltd.

website:http://www.shydtec.com

Contact:86-21-57721279

Address:Science and Technology Park, Songjiang District, Shanghai, China
Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Hebei Lead Bio-Chemicals Co., Ltd.

website:http://www.ldbiochem.com

Contact:+86-311-87826503

Address:481, Heping West Road, Shijiazhuang,China

Relevant to this article

Formal [5+3] Cycloaddition of Zwitterionic Allylpalladium Intermediates with Azomethine Imines for Construction of N,O-Containing Eight-Membered Heterocycles

Doi:10.1002/adsc.201701247
(2018)
Three new amino acid derivatives from edible mushroom Pleurotus ostreatus

Doi:10.1080/10286020.2017.1311870
(2017)
Revised stereostructure for (+)-roemecarine and synthesis of (±)-, (+)-, and (-)-roemecarine and (±)-epiroemecarine

Doi:10.1248/cpb.38.3277
(1990)
ZrOCl₂·8H₂O: An efficient catalyst for one-pot synthesis of α-amino phosphonates under solvent-free conditions

Doi:10.1080/00397910802431206
(2009)
2-Phenanthrenyl-DNA: Synthesis, pairing, and fluorescence properties

Doi:10.1002/chem.200801135
(2009)
Unusual Fragmentation of 1,1,2,2,3,3-Hexamethylindan. Methyl Group Equilibration and Multi-step Skeletal Rearrangements in the (1+) Ions Prior to the Formation of t-C4H9(1+) Other Fragment Ions

Doi:10.1002/oms.1210270416
(1992)

Article Doi