Total synthesis of (+)-compactin by a double Michael protocol

DOI: 10.1039/P19950000777

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 777 - 784 (1995)

Update date:2022-07-31

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Authors:

Hagiwara, Hisahiro

Nakano, Takashi

Kon-no, Masakazu

Uda, Hisashi

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Article abstract of DOI:10.1039/P19950000777

The total synthesis of (+)-compactin 1 has been achieved by employing a double Michael reaction of (R)-1-acetyl-3-(tert-butyldimethylsiloxy)cyclohexene 16 with methyl crotonate as the key reaction.

Full text of DOI:10.1039/P19950000777

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Product name:(R)-3-(tert-Butyl-dimethyl-silanyloxy)-1-(1-trimethylsilanyloxy-vinyl)-cyclohexene

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