Nitroalkene Inter /Intra Tandem Cycloadditions. 7. Application of (R)-(-)-2,2-Diphenylcyclopentanol as the Chiral Auxiliary

DOI: 10.1021/jo00115a042

Source and publish data:

Journal of Organic Chemistry p. 3205 - 3220 (1995)

Update date:2022-08-05

Topics:

Authors:

Denmark, Scott E.

Schnute, Mark E.

Marcin, Lawrence R.

Thorarensen, Atli

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Article abstract of DOI:10.1021/jo00115a042

Chiral enol ethers derived from (R)-(-)-2,2-diphenylcyclopentanol ((-)3) have been found to provide high levels of asymmetric induction in tandem inter <4 + 2>/intra <3 + 2> nitroalkene cycloadditions.The chiral auxiliary (>97percent ee) is readily prepar

Full text of DOI:10.1021/jo00115a042

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