Acetal Chlorination with MnO2-Trimethylchlorosilane

DOI: 10.1016/S0040-4020(01)81231-X

Source and publish data:

Tetrahedron p. 4579 - 4586 (1992)

Update date:2022-08-03

Topics:

Authors:

Bellesia, Franco

Boni, Monica

Ghelfi, Franco

Grandi, Romano

Pagnoni, Ugo M.

Pinetti, Adriano

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)81231-X

α-Chloroacetals are obtained in almost quantitative yields, by treating acetals with MnO2-trimethylchlorosilane in CH3OH:CH3CN (1:1).The halogenation is explained by a ligand-transfer process on an enolether intermediate, mediated by a Mn(IV)-chloride species.Key Words: Acetals, Aldehydes, Chlorination, Maganese(IV)oxide, Trimethylchlorosilane, Ligand-transfer

Full text of DOI:10.1016/S0040-4020(01)81231-X

Products guided by the article

Product name:2-(1-Chloro-pentyl)-[1,3]dioxolane

Cas No:16486-89-8

R&D Labs maybe for 16486-89-8

Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Hangzhou Maytime Bio-Tech Co.,Ltd.

website:http://www.maytime.com.cn

Contact:+86-571-88925295 88920965

Address:NO.2-1701 Ganghui Central Ningwei Street, Xiaoshan Hangzhou Zhejiang China
Borun Chemical Co.,Ltd.

Contact:+86-574- 87178138; 87297407

Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road
Hawks Chemical

Contact:+44 (0)161 367 9441

Address:

Relevant to this article

In Situ Methylene Capping: A General Strategy for Efficient Stereoretentive Catalytic Olefin Metathesis. the Concept, Methodological Implications, and Applications to Synthesis of Biologically Active Compounds

Doi:10.1021/jacs.7b06552
(2017)
Design and total synthesis of a fluorescent phorboxazole a analog for cellular studies

Doi:10.1016/j.bmcl.2005.10.109
(2006)
A Convergent and Stereocontrolled Synthetic Route to the Core Pentasaccharide Structure of Asparagine-Linked Glycoproteins

Doi:10.1021/jo00120a002
(1995)
Doi:10.1039/j29670000598
(1967)
Synthesis and structure-activity relationships of 6-heterocyclic- substituted purines as inactivation modifiers of cardiac sodium channels

Doi:10.1021/jm00014a011
(1995)
Synthesis and Reactions of 1,6-Dithiocyanato- and 1,6-Diiodo-1,3,5-cycloheptatrienes

Doi:10.1021/jo00202a008
(1985)

Article Doi