Aerobic Enantioselective Epoxidation of Unfunctionalized Olefins Catalyzed by Optically Active Salen-Manganese (III) Complexes

DOI: 10.1246/bcsj.67.2248

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2248 - 2256 (1994)

Update date:2022-07-30

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Authors:

Yamada, Tohru

Imagawa, Kiyomi

Nagata, Takushi

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/bcsj.67.2248

Enantioselective epoxidation of unfunctionalized olefins is achieved by the combined use of molecular oxygen and pivalaldehyde in the presence of a catalytic amount of optically active Mn(III)-salen complexes.N-Alkylimidazoles are effective axial ligands

Full text of DOI:10.1246/bcsj.67.2248

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