Ruthenium and Osmium Acyl Fluoride Complexes. Crystal Structure of *CD2Cl2

DOI: 10.1039/DT9950001073

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1073 - 1076 (1995)

Update date:2022-08-04

Topics:

Authors:

Brewer, Stuart A.

Coleman, Karl S.

Fawcett, John

Holloway, John H.

Hope, Eric G.

et al. et al.

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Article abstract of DOI:10.1039/DT9950001073

Fluoroacyl complexes of ruthenium and osmium have been identified in the oxidative addition of XeF2 to (M = Ru or Os) in dichloromethane.The mechanism of reaction, probed by the addition of BF3, involves oxidation of the metal centre by Xe

Full text of DOI:10.1039/DT9950001073

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