An extremely mild and stereocontrolled construction of 1,2-trans-β-glycosidic linkages capitalizing on benzyl-protected glycopyranosyl diethyl phosphites as glycosyl donors

DOI: 10.1016/0040-4039(95)00263-C

Source and publish data:

Tetrahedron Letters p. 2251 - 2254 (1995)

Update date:2022-07-30

Topics:

Authors:

Hashimoto, Shun-Ichi

Umeo, Kazuhiro

Sano, Ai

Watanabe, Nobuhide

Nakajima, Makoto

Ikegami, Shiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00263-C

A highly stereocotrolled 1,2-trans-β-glycosidation reaction without neighboring group participation has been developed by using benzyl-protected glycopyranosyl diethyl phosphites as glycosyl donors and boron trifluoride etherate as a promoter. The present

Full text of DOI:10.1016/0040-4039(95)00263-C

Products guided by the article

Product name:(2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-(diethoxy-phosphanyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

Cas No:165680-89-7

R&D Labs maybe for 165680-89-7

uni source industries limited

Contact:86 21 3772 9386

Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
taicang liyuan chemical co,.ltd

website:http://www.tcliyuanchem.com/productse.php

Contact:86-512-53539583

Address:Room 804,Huaxu Building,No.95,Renmin South Road,Taicang city,Jiangsu Province,China
Hefei Highzone Fine Chemical S&T CO.,LTD

Contact:86-0551-63663560

Address:room 1801 NO. 24 Shuguang RD.
Shanghai Hongbang Medical Technology CO.,. Ltd

Contact:13671516988 /18917636693

Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.
Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China

Relevant to this article

Enzymes in Organic Chemistry, Part 2: Lipase-catalysed Hydrolysis of 1-Acyloxy-2-arylethylphosphonates and Synthesis of Phosphonic Acid Analogues of L-Tyrosine

Doi:10.1016/0040-4020(95)98691-A
(1995)
Doi:10.1039/J19670001079
()
Structures of NHC Hg(II) and Ag(I) complexes and selective recognition of nitrate anion

Doi:10.1039/c4ce01519c
(2015)
Anhydrotetracycline is a Major Product of Tetracycline Photolysis

Doi:10.1021/jo00210a038
(1985)
Introducing Glycerol as a Sustainable Solvent to Organolithium Chemistry: Ultrafast Chemoselective Addition of Aryllithium Reagents to Nitriles under Air and at Ambient Temperature

Doi:10.1002/chem.201705577
(2018)
Nitroso group transfer from N-nitrososulfonamides to thiolate ions. Intrinsic reactivity

Doi:10.1016/j.tet.2006.06.060
(2006)

Article Doi