Reactions of diazo carbonyls with [PtX(CH3)(chiral diphosphine)] (X = Cl, Br, I): Chemoselectivity and diastereoselectivity of Pt-C and Pt-X carbene insertion

DOI: 10.1021/om00007a019

Source and publish data:

Organometallics p. 3178 - 3187 (1995)

Update date:2022-07-30

Topics:

Authors:

Bergamini, Paola

Costa, Emiliana

Orpen, A. Guy

Pringle, Paul G.

Smith, Martin B.

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Article abstract of DOI:10.1021/om00007a019

In polar solvents (e.g. MeCN), ethyl diazoacetate reacts with [PtXMe(S,S-diop)], where X - Cl, Br, I, to give the corresponding [PtX(CHMeCO₂Et)(S,S-diop)] as a 2:1 mixture of diastereoisomers in high yields. The major diastereoisomer of [PtCl(C

Full text of DOI:10.1021/om00007a019

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