Stereoselective Pauson-Khand reactions via the chiral [(alkyne)Co2(CO)5{P(OMe)3}]

DOI: 10.1021/om00006a062

Source and publish data:

Organometallics p. 3104 - 3107 (1995)

Update date:2022-08-03

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Authors:

Park, Hee-Jung

Lee, Bun Yeoul

Kang, Youn Kyung

Chung, Young Keun

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Article abstract of DOI:10.1021/om00006a062

Dicobalt hexacarbonyl complexes of menthyl-substituted propargyl alcohol react with PR₃ (R = OMe, Ph) to form diastereomeric mixtures of complexes 3. The isomeric complexes can be separated chromatographically. The isolated diastereomers can be

Full text of DOI:10.1021/om00006a062

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Product name:Co₂(CO)5(P(OCH₃)3)(HCCCH₂N(CH₂C₆H₅)CH₂CHCH₂)

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