Tetrahedron Letters p. 4421 - 4424 (1995)
Update date:2022-08-06
Topics: Synthesis Experimental Alkenyl Alkynyl Phosphine Oxide secondary Phosphine oxide
Baba, Gnon
Pilard, Jean-Francois
Tantaoui, Khalid
Gaumont, Annie-Claude
Denis, Jean-Marc
A general method for preparing secondary P-alkenyl and P-alkynyl phosphine oxides, compounds unknown so far, involves the condensation of the vinyl Grignard reagent or lithium acetylide on P-chloroaminophosphines followed by acidic hydrolysis of the corresponding vinyl or ethynylaminophosphines on a solid acid (Amberlyst 15).The few reported chemical properties are mainly related to the strong PH bond activation.Of special interest is the addition of a secondary vinylphosphine oxide derivative on methyl acrylate which occurs at room temperature without any catalyst.
View MoreUK SHAREPOINT INTERNATIONAL TRADE CO., LTD
Contact:44-20-31299469
Address:FLAT 107 25 INDESCON SQUARE LONDON UNITED KINGDOM E14 9DG
Dezhou Longteng Chemical Co., Ltd.
website:http://www.sodium-methoxide.cn/
Contact:0086-18866052283
Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Zhejiang Sucon Silicone Co.,Ltd
Contact:+86-575-88046692
Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Chongqing maohuan Chemicals Co., Ltd
website:http://www.bschem.com
Contact:+86 13996103726
Address:Chongqing Nan'an District Tu Town
Qingdao Xinnuo pharmaceutical Chemical Co.,Ltd
Contact:86-186-15688656
Address:50 Meters North To YuanHou Community Committee,Xifuzhen Subdistrict,Chengyang District,Qingdao
Doi:10.1021/om00009a010
(1995)Doi:10.1021/ic00125a036
(1995)Doi:10.1021/jm00065a012
(1993)Doi:10.1039/c9md00050j
(2019)Doi:10.1080/00945719708003157
(1997)Doi:10.1021/ja00132a025
(1995)